"in the philosophy of thermal and statistical physics, Maxwell's demon is athought experiment created by the Scottish physicist James Clerk Maxwellto "show that the Second Law of Thermodynamics has only a statistical certainty."It demonstrates Maxwell's point by hypothetically describing how to violate the Second Law: A container is divided into two parts by an insulated wall, with a door that can be opened and closed by what came to be called "Maxwell's demon"; the demon opens the door to allow only the "hot" molecules of gas to flow through to a favored side of the chamber, causing that side to gradually heat up while the other side cools down."
from : http://en.wikipedia.org/wiki/Maxwell's_demon
Can we do what Maxwell
believe in ?? 
 I think we can , by using some of his amazing equations in electromagnetic
and kinetic theory of gases.
all what we need is the following : 
two sphere and one of them positively charged and the other thermally insulated  , a connecting tube  and negatively ionized gas.
How does it work ?
when the ionized gas move from right tank to the left one , the atoms speed decrease due to work done against the electric field force , which is due to the left spherical tank .
not all the ionized atom can reach the left tank , the ion must have enough kinetic to overcome the electric field
How does it work ?
when the ionized gas move from right tank to the left one , the atoms speed decrease due to work done against the electric field force , which is due to the left spherical tank .
not all the ionized atom can reach the left tank , the ion must have enough kinetic to overcome the electric field
Where :
                   Ke min  is the minimum kenetic energy that the ion gas
atom must have to reach the left 
                   tank
                   E          is the electric field of the left tank .
                   C             is the electric charge of
the ionized gas atom.
                   L          is the distance between the two tanks.
What will happen ??
 First     
 : all the ionized gas atoms are at
the same temperature , which is equal to the surrounding     
                  temperature.
Second     : some of the fast
ions will reach the left tank and loosing some of its kinetic energy , ie. Its 
                 temperature will decrease .
Third       : when the ion get inside the left tank ,
the electric field is zero, so it will be cooler than the 
                 tank wall and heat will transfer from the surrounding to the tank wall to the ions .
Fourh      : the ions after some time will came back
again to the connecting tube , and start its journey to 
                 the right tank , but now electric field is in its side , pushing it , its speed and kinetic energy 
                 increasing , ie its temperature increasing and will reach the right tank at higher
temperature 
                 than the surround temperature.
Fifth        : the right tank temperature
increasing at the expense of heat energy of the surrounding .

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